DOC/LP/01/28.02.02 LESSON PLAN LP- BT2253 LP Rev. No: 01 ...

coralmonkeyMechanics

Oct 27, 2013 (3 years and 8 months ago)

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DOC/LP/0
1
/28.02.02




OBJECTIVE:


At the end of this course, the students would have learnt about classical thermodynamics.
This subject will facilitate the students
by providing basic concepts

for courses like
enzyme engineering, mass transfer
, etc.




SCOPE:


Chemical
t
hermodynamics
and Biothermodynamics
enlists thermodynamic properties of
fluids

for both ideal and non
-
ideal solutions
and understanding phase equilibria and
chemical reaction equilibria
. This course will
also
help the student to

take up
a
n

adva
nced
course in elective like Molecular modeling and Drug design. At the industry level,
students will gain knowledge about thermodynamic analysis of processes.
























LESSON PLAN

LP
-

BT2253

LP Rev. No:
0
1

Date:

27
-
12
-
12

Page
1

of

7


Sub Code & Name :
BT2253
/
CHEMICAL THERMODYNAMICS


AND BIOTHERMODYNAMICS



Branch:
BIOTECHNOLOGY



Semester
:

IV


DOC/LP/0
1
/28.02.02




Unit sylla
bus:

THERMODYNAMIC PROPERTIES OF FLUIDS


9 hrs


Volumetric properties of fluids exhibiting non ideal behavior; residual properties;
estimation of thermodynamic properties using equations of state; calculations involving
actual property exchanges; Maxwell’s

relations and applications.



Session

No


Topics to be covered


Time

(min)


Ref
/Page Numbers


Teaching
Aids

1

Introduction to Thermodynamics, Classification of
Thermodynamic properties.

50

TB 1

(1
-
15)


&

TB 2

(188
-
189)

BB


2

Volumetric properties of p
ure fluids
-
PVT behavior, Virial
equation and its application, various correlations, Simple
problems.

50

TB 1

(52
-
59)

BB

3

R
esidual properties
-
Gibbs energy, Thermodynamic diagrams
.


50

TB 1

(190
-
202
)

BB

4

Equations of state
-
Maxwells equation, Clapeyron eq
uation,
Entropy heat capacity equations.


50

TB
2 (193
-
197)

BB

5

Effect of temperature, pressure and volume on U, H and S,

C
P
-
C
V

relationship
, Problems.


50

TB 2

(202
-
209)

BB

6

Joule
-
Thomson Coefficient, Gibbs
-
Helmholtz Equation.


50

TB 2

(214
-
216)

BB

7

Problems involving actual property exchanges.

50

TB 2

(248
-
252)

BB

8

Maxwell’s relations and applications, Additional problems in
rnit
1



TB 1

(ㄸ1
-
ㄹ〩



9

oeview 潦 unit
1

an搠givi湧 ass
ig湭ent f潲 stu摥nts fr潭 rnit

灲潢oems.




-















LESSON PLAN

LP
-

BT2253

LP Rev. No: 0
1

Date:
27
-
12
-
1
2

Page 2 of 7


Sub Code & Name :
BT2253
/ CHEMICAL THERMODYNAMICS


AND BIOTHERMODYNAMICS

Unit :
I

Branch: BIOTECHNOLOGY Semester
: IV


DOC/LP/0
1
/28.02.02





Unit syllabus:
SOLUTION THERMODYNAMICS




9 hrs

Partial molar properties; concepts of chemical potential and fugacity; ideal and non
-
ideal
solutions; concepts and applications of excess properties of mi
xtures; activity coefficient;
composition models; Gibbs Duhem equation.





Session

No

Topics to be covered


Time

(min)


Ref


Teaching
Aids

1

Partial molar properties
-
physical meaning of partial molar
properties, determination of partial molar properties
.

50

TB1 (315
-
316)

TB2 (254
-
264)

TB3 (333


㌴㈩



2

Chemical 灯pentialⰠ bffect 潦 tem灥rature an搠灲essure 潮
Chemical 灯pential.



TB1 (317
-
319)

TB2 (265
-
268)

TB3 (343
-
346)

BB

3

Fugacity and Fugacity coefficient for pure species and species
in soluti
on, Generalized correlations for Fugacity coefficient,
Problems involving Fugacity and Fugacity coefficient.

50

TB1 (332
-
346)

TB 2 (269
-
274)

TB3 (353


㌵㤩



4

I摥al an搠n潮
-
ideal solutions, Raoult’s law, Henry’s law,
mr潢oems.



TBㄠ(㌴3
-
㌴㠩

TB㈠(㈷2
-
㈷㔩

TB㌠(㌶〠


㌶㔩



R

C潮ce灴s an搠a灰pications 潦 excess 灲潰orties 潦 mixtures



TB1 (349
-
351)

TB2 (298
-
299)

TB3 (366


㌷〩



6

ActivityⰠ Activity c潥fficientⰠ bffect 潦 tem灥rature an搠
灲essure 潮 Activity c潥fficientⰠ mr潢oems.



TB
2 (278
-
28
2)

TB3 (347


㌴㤩



7

di扢b auhem b煵ati潮 an搠灲潢oems relate搠t漠it.




TB2 (283
-
287)

TB3 (349
-
352)

BB

8

Additional problems in unit 2

50

TB 1 (360
-
365)

TB 2(303
-
308)


BB


9


Tutorial








-


LCD






LESSON PLAN

LP
-

BT2253

LP Rev. No: 0
1

Date:
27
-
12
-
12

Page
3

of
7


Sub Code & Name :
BT2253
/ CHEMICAL THERMODYNAMICS


AND BIOTHERMODYNAMICS

Unit:

II

Branc
h: BIOTECHNOLOGY Semester
: IV


DOC/LP/0
1
/28.02.02






Unit syllabus:
PHASE EQUILIBRIA






9 hrs

Criteria for phase equilibria; v
-
l
-
e calculations for binary and multi component systems;
liquid
-
liquid equilibria and solid
-
solid equilibria.



Session

No


Topics to be covered


Time

(min)


Ref


Teachin
g
Aids

1

Criteria of Phase equilibria
-
Constant U and V, Constant T and
V, Constant P and T.

50

TB2 (310
-
312)

TB3 (383


㌸㘩



2

Criteri潮 潦 sta扩lityⰠ sa灯p
-
li煵i搠 e煵ili扲iaⰠ mhase 摩agram
f潲 扩nary s潬uti潮sⰠ mr潢oems.



TB1 (501
-
507)

TB 2 (312
-
31
4,
326
-
330)

TB3 (
387
-

390)

BB

3

Vapor
-
liquid equilibria for multicomponent system, Problems.


50

TB1 (516
-
525)

TB 2 (362
-
366)

TB3 (391


㌹㔩



4

Binary li煵id
-
liq畩搠 e煵ili扲iaⰠ aiagramsⰠ mr潢oems.




TB ㈠2㌸ㄬ

㌸3
-
㌸㘩

TB㌠(㐴㤠


㐵㌩



R

Multico
m灯ne湴 li煵id
-
liq畩搠 e煵ilibriaⰠ aiagramsⰠ mr潢oems




TB 2 (382
-
386)

BB

6

Solid liquid equilibria and Solid vapor equilibria


50

TB1 (526
-
535)

TB3 (454
-
455)

BB

7

Additional problems in unit 3



50

TB1 (555
-
558)

TB2 (386
-
397)

BB

8

Review of unit 3 and

giving assignment for students from Unit
3 problems.


50

-

BB

9

Tutorial
-

II

50

-

LCD











LESSON PLAN

LP
-

BT2253

LP Rev. No:

0
1

Date:
27
-
12
-
12

Page
4

of
7


Sub Code & Name :
BT2253
/ CHEMICAL THERMODYNAMICS


AND BIOTHERMODYNAMICS

Unit:

III

Branch: BIOTECHNOLOGY Semester

: IV


DOC/LP/0
1
/28.02.02






Unit syllabus:
CHEMICAL REACTION EQUILIBRIA




9 hrs

Equilibrium criteria for homogeneous chemical reacti
ons; evaluation of equilibrium
constant; effect of temperature and pressure on equilibrium constant; calculation of
equilibrium conversion and yields for single and multiple reactions.


Session

No


Topics to be covered


Time

(min)


Ref


Teaching
Aids

1

E
quilibrium criteria for homogeneous chemical reactions and
its applications, Standard Gibbs energy.


50

TB1 (564
-
567)

TB2 (399
-
403)

TB3 (
470


㐷㐩




2

b煵ili扲i畭 c潮stantⰠ effect 潦 tem灥rature an搠灲essure 潮
e煵ilibri畭 c潮stantⰠmr潢oems.



TB1 (5
65
-
567)

TB 2 (404
-
420)

TB3 (475
-
476)

BB

3

Evaluation of equilibrium constant, Problems.


50

TB1 (571
-
573)

TB3 (475
-
476)

BB

4

Calculation of equilibrium conversion and yields for single
reaction and related problems.

50

TB1 (577
-
589)

BB

5

Calculation of
equilibrium conversion and yields for multiple
reaction and related problems.

50

TB1 (594
-
603)

BB

6

Other factors affecting equilibrium conversion like inert
materials, excess of reactants, products etc.,

50

TB2 (422
-
428)

TB3 (493
-

496)

BB

7

Additional p
roblems in Unit 4


50

TB 1 (604
-
611)


BB

8

Additional problems in Unit 4



50

TB 2 (441
-
450)

BB

9

Tutorial III

50

-

LCD












LESSON PLAN

LP
-

BT2253

LP Rev. No: 0
1

Date: 27
-
12
-
12

Page 5 of 7


Sub Code & Name : BT2253/ CHEMICAL THERMODYNAMICS



AND BIOTHERMODYNAMICS

Unit : IV Branch: BIOTECHNOLOGY Semester
:
IV


DOC/LP/0
1
/28.02.02







Unit syllabus:
THERMODYNAMIC ANALYSIS OF PROCESSES


9 hrs

Concept of lo
st work; entropy generation; calculation of real irreversible processes;
power cycle; Liquefaction.



Session

No


Topics to be covered


Time

(min)


Ref


Teaching
Aids

1

Calculation of Ideal work, related Problems.


50

TB 1 (612
-
616)

BB

2

Concept of lost

work, related Problems.


50

TB 1 (617
-
618)

BB

3

Thermodynamic analysis of steady state flow processes, Power
cycle.


50

TB 1 (618
-
619)

BB

4

Problems related to Power cycle.


50

TB 1 (620
-
624)

BB

5

Linde liquefaction system.


50

TB 1 (625)

BB

6

Proble
ms related to Linde liquefaction system.


50

TB1 (626
-
627)

BB

7

Entropy concepts and related problems


50

TB 1 (627
-
631)

BB

8

Review of unit 5 and giving question bank for all the 5 units
with solutions for various unsolved problems.


50

-

BB

9

Tutoria
l I
V

50

-

LCD













LESSON PLAN

LP
-

BT2253

LP Rev. No: 0
1

Date: 27
-
12
-
12

Page 6 of 7


Sub Code & Name : BT2253/ CHEMICAL THERMODYNAMI
CS


AND BIOTHERMODYNAMICS

Unit : V Branch: BIOTECHNOLOGY Semester
: IV


DOC/LP/0
1
/28.02.02









COURSE

D
ELIVERY PLAN
:


Week

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

Units

I

II

III

IV


V


TEXT BOOK (TB):

1.

Smith J.M., Van Ness H.C., Abbot M.M. Chemical Engineering
T
hermodynamics. 6
th

Edition. McGraw
-
Hill, 2001.

2.

Narayanan K.V. A Text Book of Chemical Engineering Thermodynamics.
Prentice Hall India, 2001.

3.

Gopinath Halder. Introduction to Chemical Engineering Thermodynamics, PHI,
2009.


REFERENCE BOOK (RB):

1.

Sandl
er S.I. Chemical and Engineering Thermodynamics. John Wiley,

1989.



Prepared by

Approved by

Signature





Name

P. K. Praveen Kumar


Prof.
Sulochana Somasundaram

Designation

Assistant Professor (Biotechnology)


HOD (Biotechnology)

Date

2
9
-
12
-
201
2


2
9
-
1
2
-
201
2





LESSON PLAN

LP
-

BT2253

LP Rev. No: 0
1

Date:
27
-
12
-
12

Page
7

of 7


Sub Code & Name :
BT2253
/ CHEMICAL THERMODYNAMICS


AND BIOTHERMODYNAMICS


Branch: BIOTECHNOLOGY Semester
: IV